韩福社----高性能合成橡胶工程技术中心

韩福社，性别：男，1970年出生，籍贯：甘肃，毕业于中国科学院长春应用化学研究所，获得博士学位。现任中国科学院长春应用化学研究所研究员，博士生导师。主要研究方向为天然物合成、药物合成、不对称催化、过渡金属催化的偶联方法学。
主要学习工作经历：
1989.9-1993.7, 重庆大学化工学院精细化工专业，本科
1993.9-1996.7, 大连理工大学化工学院有机化学系，硕士研究生；
1996.9-1999.9, 中科院长春应化所有机和高分子室，博士研究生；
1999.10-2001.7, 中科院上海有机所生命有机室博士后（合作者：马大为教授）。
2001.8-2003.3, 日本Ehime 大学工学部应用化学科博士后（合作者：Yutaka Watanabe 教授）；
2003.4-2006.3, 东京大学药学部天然物合成化学科，科学技振兴机构（JST）研究员（合作者：Tohru Fukuyama 教授，Hidetoshi Tokuyama教授）；
2006.4-2008.7, 日本国立物质材料研究机构，有机纳米中心，博士研究员（合作者：Dirk G. Kurth博士，德国Max-Planck 研究所； Masayoshi Higuchi 博士，物质材料研）；
2008.8-今, 中科院长春应用化学研究所，研究员/博导。

主要承担项目：
1）国家自然科学基金面上项目
2）企业合作项目
　　迄今在Chem. Soc. Rev.、J. Am. Chem. Soc.、Adv. Mater.、Chem. Commun.、Org. Lett.、Chem. Eur. J.、Adv. Synth. Catal.、ChemCatChem等发表文章60余篇，其中影响因子大于5的30余篇；申请专利13项，其中已授权7项。
所获奖项：
1）04/2003-03/2006 日本科学技术振兴机构（JST）PRESTO研究员基金。
2）08/2001- 03/2003 日本文部省Venture Business Laboratory (VBL) 特别研究员基金。
3）1999 中科院优秀博士毕业生，获伟华科技一等奖学金。
4）1996 辽宁省科技进步二等奖。
5）1991 香港社会福利基金会华新奖学金。
代表性论文：
1) “Synthetic Study Toward the Misassigned (±)-Tronoharine”, Z. Xue, Y. Li, J. Zhang, F.-S. Han,* Org. Lett., in press.
2) “Palladium-Catalyzed Enantioselective Synthesis of P-Stereogenic Phosphinamides via Desymmetric C–H Arylation”, Z.-J. Du, J. Guan, G.-J. Wu, P. Xu, L.-X. Gao, F.-S. Han,* J. Am. Chem. Soc., in press.
3) “Formal [3+3] Cyclization of Indol-2-yl Carbinol with Aza-Diene and the Subsequent Oxidative Ring Expansion Reaction for the Synthesis of Indole Azepinones”, X. Zhong, Y. Li, W.-X. Zhang, J. Zhang, S.-X. Wang, F.-S. Han,* Chem. Commun., 2014, 50, 11181.
4) “Chiral Phosphoramide-Catalyzed Enantioselective Synthesis of 2,3’-Diindoylarylmethanes from Indol-2-yl Carbinol and Indole”, S. Qi, C.-Y. Liu, J.-Y. Ding, F.-S. Han,* Chem. Commun., 2014, 50, 8605.
5) “Palladium-Catalyzed Silver-Mediated α-Arylation of Acetic acid: A New Approach for the α-Arylation of Carbonyl Compounds”, G.-J. Wu, J. Guan, F.-S. Han,* Y.-L. Zhao,* ChemCatChem, 2014, 6, 1589.
6) “Cu-Mediated Direct Aryl C–H Halogenation: a Strategy to Control Mono- and Di-Selectivity”, Z.-J. Du, L.-X. Gao, Y.-J. Lin, F.-S. Han,* ChemCatChem, 2014, 6, 123–126.
7) “Pd(II)-Catalyzed Mild C–H ortho Arylation and Intramolecular Amination Oriented by Phosphinamide Group”, J. Guan, G.-J.Wu, F.-S. Han,* Chem. Eur. J., 2014, 20, 3301.
8) “The Development of Copper-Catalyzed Aerobic Oxidative Coupling of H-Tetrazoles with Boronic Acids and an Insight into the Reaction Mechanism”, C.-Y. Liu, Y. Li, J.-Y. Ding, D.-W. Dong, F.-S. Han,* Chem. Eur. J., 2014, 20, 2373–2381.
9) “Copper-Mediated Direct Aryl C–H Cyanation with Azobisisobutyro-nitrile via a Free-radical Pathway”, H. Xu, P.-T. Liu, Y.-H. Li, F.-S. Han,* Org. Lett., 2013, 15, 3354.
10) “Transition-Metal-Catalyzed Suzuki-Miyaura Cross-Coupling Reactions: A Remarkable Advance from Palladium to Nickel Catalysts”, F. Han,* Chem. Soc. Rev., 2013, 42, 5270. (Invited review).
11) “Iron-Catalyzed Direct Synthesis of Densely Substituted Benzofurans and Naphthopyrans from Phenolic Compounds and Propargylic Alcohols” F.-Q. Yuan, F. Han*, Adv. Synth. Catal., 2013, 355, 537.
12) “Al-Catalyzed Facile Construction of Quaternary C–C Bonds via the Allylic Substitution of tertiary Alcohols: A Concise Formal Synthesis of (±)-Mersicarpine”, X. Zhong, Y. Li, F. Han*, Chem. Eur. J., 2012, 18, 9784.
13) “Ni-Catalyzed Construction of C–P Bond from Electron-deficient Phenols via the in situ Aryl C–O Activation by PyBroP”, Y.-L. Zhao, G.-J. Wu, F. Han*, Chem. Commun., 2012, 48, 5868.
14) “Ni(dppp)-Catalyzed Cross-coupling of Aryl Halides with Dialkylphosphite, Diphenylphosphine oxide, and Diphenylphosphine”, Y.-L. Zhao, G.-J. Wu, Y. Li, L.-X. Gao, F. Han*, Chem. Eur. J., 2012, 18, 9622.
15) “Synthesis of Densely Substituted a,b,g,d-Dienones via the PdII-Catalyzed Allylation, H-Migration, and Aerobic Oxidative d-Hydride Elimination Cascade”, F.-Q. Yuan, F. Han*, Org. Lett., 2012, 14, 1218.
16) “Efficient Synthesis of 2,5-Disubstituted Tetrazoles via the Cu2O-Catalyzed Aerobic Oxidative Direct Cross-coupling of N-H Free Tetrazoles with Boronic Acids”, Y. Li, L.-X. Gao, F. Han*, Chem. Commun., 2012, 48, 2719.
17) “PdCl2(dppf)-Catalyzed in situ Coupling of 2-Hydroxypyridines with Aryl Boronic Acids Mediated by PyBroP and the one-pot Chemo- and Regioselective Construction of two Distinct Aryl-Aryl Bonds”, S.-M. Li, J. Huang, G.-J. Chen, F. Han*, Chem. Commun., 2011, 47, 12840.
18) “PdCl2-Catalyzed Efficient Allylation and Benzylation of Heteroarenes under Ligand, Base/Acid, and Additive-Free Conditions”, F.-Q. Yuan, L.-X. Gao, F. Han*, Chem. Commun., 2011, 47, 5289.
19) “Ni-Catalyzed Cross-Coupling of Phenols and Aryl Boronic Acids via an in situ Phenol Activation Mediated by PyBrOP”, G. J. Chen, J. Huang, L. X. Gao, F. Han*, Chem. Eur. J., 2011, 17, 4038.
20) “A Highly Practical and Reliable Nickel Catalyst for Suzuki-Miyaura Coupling of Aryl Halides” Y.-L. Zhao, Y. Li, S.-M. Li, Y.-G. Zhou, F.-Y. Sun, L.-X. Gao, F.-S. Han*, Adv. Synth. Catal., 2011, 353, 1543.
21) “Highly Efficient Suzuki-Miyaura Coupling of Aryl Tosylates and Mesylates Catalyzed by Stable, Cost-effective [1,3-Bis(diphenylphosphino)propane]nickel(II) Chloride {Ni(dppp)Cl2} with only 1 mol % Loading”, H. Gao, Y. Li, Y. G. Zhou, F. Han,* Y. J. Lin*, Adv. Synth. Catal., 2011, 353, 309.
22) “An Organogel Formed from a cyclic b-aminoalcohol”, C. Kang, Z. Bian, Y. He, F. Han, X. Qiu, L.-X. Gao, Chem. Commun., 2011, 47, 10746.
23) “Reliable and Diverse Synthesis of Aryl Azides via Copper-Catalyzed Coupling of Boronic Acids/Esters with TMSN3”, Y. Li, L. X. Gao, F. Han*, Chem. Eur. J., 2010, 16, 7969.
24) “Aryl Phosphoramides: Useful Electrophiles for Suzuki-Miyaura Coupling Catalyzed by NiCl2/dppp System”, Y. L. Zhao, Y. Li, Y. Li, L. X. Gao, F. Han*, Chem. Eur. J., 2010, 16, 4991.
25) “Luminescence Properties of Metallo-supramolecular Coordination Polymers Assembled from Pyridine Ring Functionalized Ditopic Bis-terpyridine and Ru(II) ions” F. Han, M. Higuchi, T. Ikeda, Y. Negishi, T. Tsukuda, D. G. Kurth, J. Mater. Chem., 2008, 18, 4555.
26) “Metallo-Supramolecular Polyelectrolytes Self-assembled from Various Pyridine Ring Substituted Bis-terpyridines and Metal Ions: Photophysical, Electrochemical and Electrochromic Properties” F. Han, M. Higuchi, D. G. Kurth, J. Am. Chem. Soc., 2008, 130, 2073.
27) “Metallo-Supramolecular Polymers Based on Functionalized Bis-terpyridines as Novel Electrochromic Materials” F. Han, M. Higuchi, D. G. Kurth, Adv. Mater., 2007, 19,3928.
28) “Design and Synthesis of Thiazoline-Thiazole Hybrid Macrocycles Possessing Strong Affinity to Pb2+ and Cd2+” F. Han, H. Tokuyama, T. Fukuyama, Chem. Comm., 2007, 3444.
29) “Novel Structural Motifs Consisting of Chiral Thiazolines: Synthesis, Molecular Recognition, and Anticancer Activity” F. Han, H. Osajima, M. Cheung, H. Tokuyama, and T. Fukuyama, Chem. Eur. J. 2007, 13,3026 (Selected as inside cover page).
30) “Diverse Synthesis of Novel Bisterpyridines via Suzuki-Type Cross-Coupling” F. Han, M. Higuchi, D. Kurth, Org. Lett., 2007, 9, 559-562.
31) “Synthesis of Chiral Cyclic Oligothiazolines: A Novel Structural Motif for a Macrocyclic Molecule”, F. Han, H. Osajima, M. Cheung, H. Tokuyama, and T. Fukuyama, Chem. Comm. 2006, 1757-1759.