胡雁鸣----高性能合成橡胶工程技术中心

研究领域：

烯烃及共轭二烯烃配位聚合催化剂的开发、功能性聚合物的合成。

教育背景:

l 2005年–2008年日本京都大学高分子化学工学博士

l 2001年–2004年长春应用化学研究所高分子化学与物理理学硕士

l 1989年–1993年北京理工大学高分子材料工学学士

工作经历:

Ø 2008年12月–2014年3月大连理工大学化工学院副教授

Ø 2008年 2月–2008年3月 University of Texas at Austin 访问学者

Ø 2004年7月–2005年8月中国石油锦州石化公司技术中心高级工程师　　

Ø 1993年7月–2001年8月中国石油锦州石化公司研究院工程师

承担或参加的科研项目：

作为项目负责人承担的项目：

Ø 基于配位聚合方法合成星形高顺式-1,4 聚丁二烯（国家自然科学基金项目 20974016）

Ø 教育部留学回国人员科研启动基金项目[教外司留(2010)1174]

参加的科研项目包括：

Ø 稀土催化顺丁橡胶产业化关键技术(国家863计划)

Ø 基于活性阴离子聚合精确合成功能性高枝化星形梳状聚合物(国家自然科学基金重点项目21034001)

Ø 间同1,2-聚丁二烯的合成及性能研究(国家自然科学基金项目20274046)

Ø 高乙烯基聚丁二烯橡胶（HV-BR）的研究与开发(国家科技部“十五”攻关项目)。

Ø 合成橡胶用新型抗氧剂体系的开发（中国石油项目）

发表文章

(1) Hu, Y.*; Zhao, Z.; Bai, X.; Yuan, X.; Zhang, X.; Masuda, T. Organoborane-containing polyacetylene derivatives: synthesis, characterization, and fluoride-sensing properties, RSC Adv., 2014, 4, 55179–55186.

(2) Wang, F.; Dong, B.; Liu, H.; Guo, J.; Zheng, W.; Zhang, C.; Zhao, L.; Bai, C.; Hu, Y.*; Zhang, X.* Synthesis of Block Copolymers Containing Polybutadiene Segments by Combination of Coordinative Chain Transfer Polymerization,Ring-Opening Polymerization, and Atom Transfer Radical Polymerization, Macromol. Chem. Phys., 2014, DOI: 10.1002/macp.201400465

(3) Liu, H.; Wang, F.; Jia, X.; Liu, L.; Bi, J.; Zhang, C.; Zhao, L.; Bai, C.; Hu, Y.*; Zhang, X.* Synthesis, characterization, and 1,3-butadiene polymerization studies of Co(II), Ni(II), and Fe(II) complexes bearing 2-(N-arylcarboximidoylchloride)quinoline ligand, J. Mol. Cat A: Chem., 2014, 391, 25–35.

(4) Liu, H.; Wang, F.; Liu, L.; Jia, X.; Zheng, W.; Guo, J.; Zhang, C.; Bai, C.; Hu, Y.*; Zhang, X.* Synthesis, characterization, and ethylene polymerization behaviors of late-transition metal complexes coordinated with chlorinated bis(arylimino)pyridine ligand, Polymer, 2014, 55, 4611–4618.

(5) Liu, H.; Wang, F.; Liu, L.; Dong, B.; Zhang, H.; Bai, C.; Hu, Y.*; Zhang, X.* Synthesis, characterization and 1,3-butadiene polymerization behaviors of three ONO, ONN, and NNN tridentate Co(II) complexes, Inorg. Chim. Acta, 2014, 421, 284–291.

(6) Inoue, R.; Kanaya, T.; Hu, Y.; Masuda, T.; Nishida, K.; Yamamuro, O. Relationship between the local dynamics and gas permeability of polyacetylenes containing polymethylated indan/tetrahydronaphtalene moieties, Polymer, 2014, 55, 182–186.

(7) Hu, Y.*; Zhang, C.; Liu, X.; Gao, K.; Cao, Y.; Zhang, C.; Zhang, X. Methylaluminoxane-Activated Neodymium Chloride Tributylphosphate Catalyst for Isoprene Polymerization, J. Appl. Polym. Sci., 2014, DOI: 10.1002/APP.40153.

(8) Zhao, Z.; Wang, Z.; Zhang, C.; Wang, Y.; Li, Z.; Hu, Y.; Xiao, X. Polar Polystyrene-Isoprene-Styrene Copolymers with Long Polybutadiene Branches, J. Appl. Polym. Sci., 2014, DOI: 10.1002/APP.40303.

(9) 胡雁鸣,高可可,张丛峥,李战胜,增田俊夫. 物理老化对聚[1-(4-三甲基硅基)苯基-2-苯乙炔]膜气体渗透性能的影响, 化学工业与工程, 2014, 31(1), 53–56.

(10) 齐晓梅,胡雁鸣,张贺新,张春雨,张学全. 外给电子体对MgCl₂负载TiCl₄催化剂催化乙烯丙烯共聚合的影响, 合成橡胶工业, 2014, 37(6), 413–416.

(11) Zhang, Y.; Gao, K.; Zhao, Z.; Yue, D.; Hu, Y.*; Masuda, T. Helical Poly(phenylacetylene)s Containing Schiff-Base and Amino Groups: Synthesis, Secondary Structures, and Responsiveness to Benzoic Acid, J. Polym. Sci., Part A: Polym. Chem., 2013, 51, 5248–5256.

(12) Hu, Y.*; Dong, W.; Masuda, T.* Novel Methylaluminoxane-Activated Neodymium Isopropoxide Catalysts for 1,3-Butadiene Polymerization and 1,3-Butadiene/Isoprene Copolymerization, Macromol. Chem. Phys., 2013, 214, 2172–2180.

(13) Jia, X.; Hu, Y.*; Dai, Q.; Bi, J.; Bai, C.; Zhang, X.* Synthesis of Syndiotactic cis-1,4-Polypentadiene by Using Ternary Neodymium-based Catalyst, Polymer, 2013, 54, 2973–2978.

(14) Wang, F.; Liu, H.; Zheng, W.; Guo, J.; Zhang, C.; Zhao, L.; Zhang, H.; Hu, Y. *; Zhang, X.* Fully-reversible and semi-reversible coordinative chain transfer polymerizations of 1,3-butadiene with neodymium-based catalytic systems, Polymer, 2013, 54, 6716–6724.

(15) Wang, B.; Bi, J.; Zhang, C.; Dai, Q.; Bai, C.; Hu, Y.*; Zhang, X.*; Jiang, L. Highly active and trans-1,4 specific polymerization of 1,3-butadiene catalyzed by 2-pyrazolyl substituted 1,10-phenanthroline ligated iron (II) complexes, Polymer, 2013, 54, 5174–5181.

(16) Jia, X.; Liu, H.; Hu, Y.*; Dai, Q.; Bi, J.; Bai, C.; Zhang, X.* Highly active and cis-1,4 selective polymerization of 1,3-butadiene catalyzed by cobalt(II) complexes bearing α-diimine ligands, Chin. J. Cat., 2013, 34, 1560–1569.

(17) Li, T.; Hu,Y.; Zhang, H.; Shi, Z.; He, G.; Wang, Y. Shen, K. Li, Y. “One-Pot” Random Terpolymerization of Styrene, Isoprene and Butadiene with Nd-Based Catalyst, J. Appl. Polym. Sci., 2013, DOI: 10.1002/APP.39327.

(18) Wang, B.; Gong, D.; Bi, J.; Dai, Q.; Zhang, C.; Hu, Y.*; Zhang, X.*; Jiang, L. Synthesis, characterization and 1,3-butadiene polymerization behaviors of cobalt complexes bearing 2-pyrazolyl-substituted 1,10-phenanthroline ligands, Appl. Organometal. Chem., 2013, 27, 245–252.

(19) 刘贤光,张春庆,胡雁鸣*,张学全. 钕系催化剂合成高顺式窄分布聚丁二烯, 高分子材料科学与工程, 2013, 29(6), 28–31.

(20) 刘贤光,张春庆,张玉玲,胡雁鸣*,张学全.以新癸酸钕/正丁基锂/氯化二乙基铝催化体系合成聚丁二烯, 合成橡胶工业, 2013, 36(4), 264–267.

(21) 胡雁鸣*,张丛峥,李战胜,张学全,增田俊夫. 老化对聚(1-三甲基硅基-1-丙炔)气体渗透性能的影响, 应用化学, 2013, 30(2), 138–142.

(22) 许蔷,胡雁鸣,李杨*,史正海,王艳色,王玉荣. 用甲基铝氧烷活化的氯化稀土催化剂合成高顺式窄分布聚丁二烯, 高分子学报, 2013, 1, 36–42.

(23) Wang, F.; Zhang, C.; Hu, Y.; Jia, X.; Bai, C.; Zhang, X*. Reversible coordinative chain transfer polymerization of isoprene and copolymerization with ε-caprolactone by neodymium-based catalyst, Polymer, 2012, 53, 6027–6032.

(24) Li, W.; Li, Y.; Hu, Y.; Wang, Y. Synthesis and characterisation of HSIBR used as viscosity index improver for lubricants, Lubrication Science 2012, 24, 188–197.

(25) 胡雁鸣*, 袁学程, 李战胜, 增田俊夫. 含有联苯侧基聚乙炔的合成及其气体渗透性能, 应用化学, 2012, 29(6), 617–622.

(26) 孔春丽, 胡雁鸣*, 李杨, 史正海, 张学全. 磷酸酯钕系催化剂合成高顺式丁二烯-异戊二烯共聚物,合成橡胶工业, 2012, 35, 356–360.

(27) 孔春丽, 胡雁鸣*, 李杨, 于晓燕. 磷酸酯钕系催化剂合成窄分子量分布高顺式聚异戊二烯, 合成橡胶工业, 2012, 35, 187–191.

(28) 常丽, 胡雁鸣, 李杨*, 史正海, 吕权, 王玉荣. 本体原位法制备高抗冲聚苯乙烯 I. 引发剂的影响, 合成树脂及塑料, 2012, 29, 6–10.

(29) 孔春丽, 李杨, 胡雁鸣, 王玉荣. FTIR与C NMR研究丁戊共聚物的微观结构及序列分布, 分析测试学报, 2012, 31(10), 1254–1259.

(30) Hu, Y.; Jia, Z.; Li, Y.*; Chang, L.; Wang, Y. Synthesis and Impact Properties of in situ Bulk Made ABS Resins Toughened by High cis-1,4 Polybutadiene, Mater. Sci. Eng. A, 2011, 528, 6667–6672.

(31) 胡雁鸣*, 许蔷. 取代聚炔的合成及其分离性能, 高分子通报, 2011, 9, 100–110.

(32) 胡雁鸣, 孔春丽, 李杨*, 常丽, 徐端端, 王玉荣. 苯乙烯存在下稀土催化合成窄分布高顺式聚丁二烯,高分子材料科学与工程，2011, 27, 9–11.

(33) 徐端端, 胡雁鸣, 李杨*, 张学全, 王玉荣, 张春庆. 用稀土催化剂制备高顺式丁二烯-异戊二烯共聚物, 合成橡胶工业, 2011, 34, 272–276.

(34) 常丽, 胡雁鸣, 李杨*, 史正海, 吕权, 王玉荣. 本体原位法制备高抗冲聚苯乙烯, 石油化工, 2011, 40, 850–855.

(35) Hu, Y., Hattori, K., Fukui, A., Shiotsuki, M., Sanda, F., Masuda, T.* Synthesis and Gas Permeation Properties Of Various Si-containing Poly(diarylacetylene)s and Their Desilylated Membranes, Polymer 2010, 51, 1548–1554.

(36) Hu, Y., Shimizu, T., Hattori, K., Shiotsuki, M., Sanda, F., Masuda, T.* Synthesis and Gas Permeation Properties of Poly(diarylacetylene)s Having Substituted and Twisted Biphenyl Moieties, J. Polym. Sci. Part A: Polym. Chem. 2010, 41, 861–868.

(37) 李嵬，李杨*，胡雁鸣，王玲芳，崔冬梅，王玉荣. 完全交替结构乙烯-丙烯共聚物的制备与表征, 高分子学报, 2010, 8, 961–965.

(38) Gong, D., Dong, W., Hu, Y., Bi, J., Zhang, X.*, Jiang, L. Syndiotactically Enriched 1,2-Selective Polymerization of 1,3-Butadiene Initiated by Iron Catalysts Based on a New Class of Donors, Polymer 2009, 50, 5980–5986.

(39) Zhang, X., Li, Y.*, Zhang, C., Hu, Y., Song, S., Guo, H., Wang, Y. Synthesis and Characterization of Stereotriblock Polybutadiene Containing Crystallizable High trans-1,4-Polybutadiene Block by Barium Salt of Di(ethylene glycol) Ethylether/Triisobutylaluminium/Dilithium, Polymer 2009, 50, 5427–5433.

(40) Fukui, A., Hattori, K., Hu, Y., Shiotsuki, M., Sanda, F., Masuda, T.* Synthesis, Characterization, and High Gas Permeability of Poly(diarylacetylene)s Having Fluorenyl Groups, Polymer 2009, 50: 4159–4165.

(41) Hu, Y., Shiotsuki, M., Sanda, F., Freeman, B. D., Masuda, T.* Synthesis and Properties of Indan-Based Polyacetylenes That Feature the Highest Gas Permeability among All the Existing Polymers, Macromolecules, 2008, 41, 8525–8532.

(42) Hu, Y., Shiotsuki, M., Sanda, F., Masuda, T.* Synthesis and Extremely High Gas Permeability of Polyacetylenes Containing Polymethylated Indan/Tetrahydronaphthalene Moieties, Chem. Commun. 2007, 4269–4270.

(43) Hu, Y., Liu, R., Sanda, F., Masuda, T.* Synthesis of Glutamic Acid-based Dendritic Helical Poly(phenylacetylene)s, Polym. J. 2008, 40, 143–147.

(44) Hu, Y., Liu, R., Sanda, F., Masuda, T.* Synthesis and Chiroptical Properties of Poly(phenylacetylene)s Carrying Two Amino Acid Moieties per Monomer Unit, Polym. Bull. 2008, 60, 159–167.

(45) Hu, Y., Shiotsuki, M., Masuda, T.* Synthesis and Properties of Various Poly(diarylacetylenes) Containing Siloxy and Hydroxy Groups, J. Polym. Sci. Part A: Polym. Chem. 2007, 45, 4487–4495.

(46) Hu, Y., Sakaguchi, T., Shiotsuki, M., Sanda, F., Masuda, T.* Synthesis and Properties of Poly(diphenylacetylenes) Containing Siloxy and Halogen/methyl Groups and Their Desilylated Membranes, Polymer 2007, 48, 43–49.

(47) Hu, Y., Shiotsuki, M., Sanda, F., Masuda, T.* Synthesis and Properties of Substituted Polyacetylenes Having Cyclohexyl Groups, Polym. J. 2007, 39, 968–974.

(48) Kono, T., Hu, Y., Masuda, T.*, Tanaka, T., Priestley, R. D., Freeman, B. D. Effect of Fumed Silica Nanoparticles on the Gas Permeation Properties of Substituted Polyacetylene Membranes, Polym. Bull. 2007, 58, 995–1003.

(49) 卢军, 胡雁鸣, 张学全, 黄葆同. 间同1,2-聚丁二烯的结构和结晶动力学研究, 东北大学学报, 2007, 28, 909–912.

(50) Hu, Y., Sakaguchi, T., Shiotsuki, M., Sanda, F., Masuda, T.* Synthesis and Characterization of Poly(diphenylacetylenes) Containing both Hydroxy and Halogen/alkyl Groups as Gas Separation Membranes, J. Membr. Sci. 2006, 285, 412–419.

(51) Hu, Y., Sakaguchi, T., Shiotsuki, M., Sanda, F., Masuda, T. Synthesis and Gas Permeation Properties of Poly(diphenylacetylenes) Having Bulky Alkyl/silyl and Hydroxy Groups, J. Membr. Sci. 2006, 282, 423–429.

(52) Lu, J., Hu, Y., Zhang, X., Bi, J., Dong, W. M., Jiang, L., Huang, B. Fe(2-EHA)₃/Al(i-Bu)₃/Hydrogen Phosphite Catalyst for Preparing Syndiotactic 1,2-Polybutadiene, J. Appl. Polym. Sci. 2006, 100, 4265–4269.

(53) Kono, T., Sakaguchi, T., Hu, Y., Shiotsuki, M., Sanda, F., Masuda, T. Synthesis and Properties of Poly(phenylacetylenes) Having Two Polar Groups or One Cyclic Polar Group on the Phenyl Ring, J. Polym. Sci., Part A: Polym. Chem. 2006, 44, 5943–5953.

(54) 郭玉,胡雁鸣, 董为民, 姜连升, 张学全.温度对以二乙基亚磷酸酯为给电子体的铁系催化剂聚合异戊二烯的影响,合成橡胶工业 , 2006, 29, 65–66.

(55) 胡雁鸣, 董为民, 姜连升, 张学全.改性甲基铝氧烷活化的铁系催化剂聚合异戊二烯, 高分子材料科学与工程, 2005, 21, 106–109.

(56) 胡雁鸣, 董为民, 姜连升, 张学全. 以亚磷酸二乙酯为第三组分的铁系催化体系催化异戊二烯聚合,合成橡胶工业, 2004, 27, 344–347.

(57) 胡雁鸣, 董为民, 姜连升, 张学全,郭玉,曹丽辉.铁系催化剂上合成高乙烯基聚丁二烯的研究I.三苯基磷酸酯的影响,催化学报, 2004, 25, 664–668.

(58) Chen, Y., Yang, D., Hu, Y., Zhang, X. Effects of Crystal Growth Conditions on Morphology of Crystalline Syndiotactic 1,2-Polybutadiene, Cryst. Growth Des. 2004, 4, 117–121.

(59) 陈晔,杨德才,胡雁鸣,张学全. 结晶性间同立构1,2-聚丁二烯的单晶结构, 高等学校化学学报, 2003, 24, 2321–2323.

(60) 陈晔,杨德才,胡雁鸣,张学全. 间同立构1,2-聚丁二烯的合成和形态结构研究,高等学校化学学报, 2003, 24, 2119–2121.